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Biodiesel Production

Transcript

Biodiesel Production

An alternative to Petroleum Diesel

INDEX

1. Research Question

8. Areas of Concerns

2. Aim

3. Hypothesis

4. Variables

5. Methods

6. Setup

7. EE Outline

9. Secondary Sources

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To what extent do the physical and chemical properties of manufactured Biodiesel vary with the physical and chemical properties of petroleum diesel when manufactured from different oils having different carbon chain lengths.

Research Question

Aim

To find out the chemical and physical properties, by comparing 3 properties of Biodiesels - Viscosity, Calorific Value & Flash Point

In simpler words:
Viscosity - resistance to the movement of a fluid
Calorific Value - amount of heat liberated by burning unit mass of fuel at STP
Flash Point - lowest temperature at which vapours of a combustible liquid can be ignited

hypothesis

Biodiesel produced from an oil with a longer carbon chain length will increase the calorific value, the viscosity & the flash point of the fuel.

Castor Oil

C57H104O9

Palm Oil

C15H29O5

Sunflower Oil

C16-18

Rapeseed Oil

C22H42O2

Mustard Oil

C4H5NS

A moderately lower viscosity, lower flash point and a higher calorific value is prefered in fuels. I predict that Biodiesel produced from Rapeseed oil will have the most similar chemical and physical properties to that of petroleum diesel.

Variables

Castor oil
Rapeseed oil
Palm oil
Sunflower oil
Mustard oil
Methanol
Ethanol

dependent

Calorific Value
Viscosity
Flash Point

Independent

Temperature

Agitation Speed
Amount of Catalyst
Catalyst concentration
Molar ratio of Alcohols

control

Methods

Step 1 - Manufacture Biodiesel by transesterifcation reaction in which 1 mole of triglycerides (vegetable oil) reacts with 3 moles of alcohol to produce 3 moles of alkyl esters (biodiesel) and 1 mole of glycerol, a co-product.

Methods

Step 2 - Place the mixture in a seperatory funnel to seperate biodiesel and the glycerol.

Step 3 - To calculate the viscosity - Heat the biodiesel before hand at a certian temperature and measure it, either by a mechanical viscosity meter or a manual viscosity meter.

Step 4 - To calculate Flash Point - Keep on incresing the temperature of the biodiesel and record the minimum temperature at which the vapours of biodiesel catch fire.

Step 5 - To calculate the calorifc value - Set up a self made calorimeter and use the principle of mixtures formula.

Heat given out by fuel = heat taken in by the water and the container

Setup

EE Outline

  • Title - Research question
  • Introduction - why i choose this topic and research question
  • Background information - Biodiesel, Viscosity, Calorifc Value and Flash Point, transesterification reaction, Factors affecting these parameters.
  • Hypothesis - results I predict for my 3 experiments
  • Variables - dependent, independent and controlled
  • Chemicals
  • Safety Requirements
  • Apparatus
  • Labelled Set up
  • Methods
  • Body paragraphs - Raw and processed data with calculations
  • Conclusion linked to hypothesis - Limitations
  • Evaluation/ Reflection - random and systematic errors
  • Bibliography

Areas of concern

TIme

Reflecting on the reliability of my Sources

Availibilty of Oils

Secondary sources

  • Biodieseleducator.org
  • Osorio-González CS, Gómez-Falcon N, Sandoval-Salas F, Saini R, Brar SK, Ramírez AA. Production of Biodiesel from Castor Oil: A Review. Energies. 2020; 13(10):2467. https://doi.org/10.3390/en13102467
  • Revised 11/2015; Chem 1101 Lab- EXPERIMENT: CALORIMETRY AND HEAT OF NEUTRALIZATION
  • Baskar Thangaraj, Pravin Raj Solomon, Bagavathi Muniyandi, Srinivasan Ranganathan, Lin Lin, Catalysis in biodiesel production—a review, Clean Energy, Volume 3, Issue 1, March 2019, Pages 2–23, https://doi.org/10.1093/ce/zky020

THANKS